The potential of tandem mass spectrometry (MS/MS) as a stand-alone technique in the structural analyses of an oviposition-deterring pheromone (ODP, 1) is reviewed. Two facets of the salt-like glycolipid structure of 1 were of major interest in this context: the substitution pattern of the lipid back
Analysis of the chemical defence system in an insect larva by tandem mass spectrometry
✍ Scribed by Hans Gfeller; Urs P. Schlunegger; Urs Schaffner; Jean-Luc Boevé; Istvan Ujvary
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 356 KB
- Volume
- 30
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
Larvae of the sawfly Rhadinoceraea nodicornis Konow (Hymenoptera, Tenthredinidae) living on the plant Veratrum album L. (Liliales, Melanthiaceae) are efficiently protected against ants and spiders. Moreover, when their haemolymph was offered in a sugar solution, ants were still deterred. The chemical defence system of these larvae was investigated and the structures of the biologically active compounds determined by tandem mass spectrometry. Plant‐derived alkaloids both in original and metabolized form were found in the larval haemolymph.
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