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Analysis of the 3Π0,1−X 1Σ+ transition of gallium monoiodide

✍ Scribed by J. Borkowska-Burnecka; W. Żyrnicki

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 397 KB
Volume: 238
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00399-o

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✦ Synopsis

Bands of the A 3IIo-X 1~+ and B 3II1-X 1~+ transitions of the 69GaI and 71GaI molecules, lying in the range 370-420 nm, have been excited in a hollow cathode discharge and analyzed. Six bands of the A-X system have been analyzed rotationally and the rotational constants of the A 3I-I 0 state determined. Former band measurements and vibrational assignments have been revised and extended. Vibrational constants of the A0 +, B1 and X0 + states of the 69GaI molecule have been determined using band origins and for the excited states these constants are an improvement on previous results. Franck-Condon factors for the A-X and B-X bands have been calculated using the molecular constants obtained.

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