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Analysis of polystyrene-b-polyisoprene copolymers by coupling of liquid chromatography at critical conditions to NMR at critical conditions of polystyrene and polyisoprene

โœ Scribed by Pritish Sinha; Wolf Hiller; Vasilios Bellas; Harald Pasch


Book ID
112136166
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
857 KB
Volume
35
Category
Article
ISSN
1615-9306

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## Abstract In this study, liquid chromatography at critical conditions (LCCC) is used to determine the block lengths and molar masses of polydimethylsiloxaneโ€__block__โ€polystyrene copolymers synthesized __via__ atom transfer radical polymerization (ATRP) techniques. In addition, the analysis allow

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## Abstract Blends of polystyrene (PS) and polyisoprene (PI) were analysed by onโ€line hyphenation of LC at critical conditions and ^1^Hโ€NMR. Chromatography at critical conditions was established for both PS and PI. At both critical conditions, a perfect separation into the blend components was achi