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Analysis of Norrish type II reactions by molecular mechanics methodology

✍ Scribed by Ronald R. Sauers; Karsten Krogh-Jespersen

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
264 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

Force field parameters have been developed that reproduce the triplet state ab initio geometries of two ketones. Transition state energies and geometries have been computed for a variety of Norrish Type II reactions. A correlation has been found between overall reaction and transition state strain energy.

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