𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Analysis of kinetic parameters from batch and integral reaction experiments

✍ Scribed by John H. Seinfeld; George R. Gavalas

Publisher
American Institute of Chemical Engineers
Year
1970
Tongue
English
Weight
455 KB
Volume
16
Category
Article
ISSN
0001-1541

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The estimation of chemical reaction rate constants from experimental batch or integral reactor data is examined. Consideration is given to the effect on the accuracy of the parameter estimates of the number of concentrations measured, extending the range of measurements to higher conversions, and experimental errors. The study is based on estimates of two rate constants obtained by quasilinearization in the pyrolytic dehydrogenation of benzene. It is found that if fewer than the number of independent components are to be measured, certain components produce better parameter estimates than others. The level of experimental errors is by far the most significant factor in obtaining reliable parameter estimates.

📜 SIMILAR VOLUMES

Site-specific experiments on folding/unf
Site-specific experiments on folding/unfolding of Jun coiled coils: Thermodynamic and kinetic parameters from spin inversion transfer nuclear magnetic resonance at leucine-18
✍ D. André d'Avignon; G. Larry Bretthorst; Marilyn Emerson Holtzer; Kathleen A. Sc 📂 Article 📅 2006 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 369 KB

## Abstract The 32‐residue leucine zipper subsequence, called here Jun‐lz, associates in benign media to form a parallel two‐stranded coiled coil. Studies are reported of its thermal unfolding/folding transition by circular dichroism (CD) on samples of natural isotopic abundance and by both equilib