Capillary viscometer measurements for a number of polyethylenes and polystyrenes reveal deviations from linearity in plots of applied pressure versus capillary length to diameter ratio, at constant rates of shear, resulting in apparently negative end corrections. This is contrary to previous physica
Analysis of flow data on molten polymers
โ Scribed by M.M. Cross
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- English
- Weight
- 335 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0014-3057
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โฆ Synopsis
On the basic assumption that viscosity is a continuous function of shear rate it is deduced that any non-Newtonian fluid should conform to a flow equation of the form
where ~ is the viscosity at shear rate D, 7/0 and ~7o~ are limiting values at respectively zero and infinite rate of shear, and = is a constant.
With a value of ,~ for the index n the equation is applied successfully to published data on both polystyrene and polyethylene melts.
An analysis by Bingham (I) in which the non-Newtonian flow of polymer melts is attributed solely to elasticity is shown to be inadequate.
๐ SIMILAR VOLUMES
The flow of molten polymer through porous media has been investigoted o t constant tempemtures and flow rates. Temperatures of 375", 400", and 425"F., flow rates from 12 to 60 g./min. and particle sizes from 0.054 in. to 6 mm. in diameter were studied. A modified Darcy's law was developed using the