Analysis of carbon-13 nuclear magnetic resonance shifts in terms of substituent parameters: statistical comparison of dual and single substituent parameter treatments
β Scribed by Cornelis, Andre; Lambert, Stephane; Laszlo, Pierre; Schaus, Philippe
- Book ID
- 120988499
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 675 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Carbonβ13 chemical shift parameters for equatorial and axial substituents in cyclohexane are reported for methyl, ethyl, isopropyl, methoxy and phthalimido substituents. The usefulness of the alkyl parameters is demonstrated by the agreement between calculated and observed ^13^C shifts
## Abstract Earlier assignments of ^13^C NMR signals to Cβ6 and Cβ7 in 5,5βdimethylβ2βnorbornanone (1) based on lanthanideβinduced shifts are interchanged on the basis of studies of deuteriumβlabeled derivatives of 1. The revised assignments are in accord with predictions based on substituent param