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Analogs of reduced rubredoxin: positive shifts of redox potentials of cysteine-containing peptide iron(II) complexes

✍ Scribed by Ueyama, Norikazu; Nakata, Michio; Fuji, Michiaki; Terakawa, Toshitsugu; Nakamura, Akira

Book ID
126881708
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
765 KB
Volume
24
Category
Article
ISSN
0020-1669

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The absorption, CD, and 1 H-and 19 F-nmr spectroscopic features of Fe(II) complexes with a series of cysteine-containing oligopeptides were investigated in aqueous (H 2 O or D 2 O) 10% Triton X-100 micelle solution. The complexes with distal aromatic rings, [Fe(Zcys-Pro-Leu-cys-Gly-X) 2 ] 20 (Z Γ… be