Anaerobic functionalization of remote unactivated carbon-hydrogen bond by polyoxometalates

✍ Scribed by Craig L. Hill; Roman F. Renneke; Lucille Combs

• Book ID: 104203833
• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 855 KB
• Volume: 44
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(01)86244-x

✦ Synopsis

AWtmct The cxctted states do zepreacmtattvc hucqoiytu~te. ~i=W~20109-. and a rqment8tk bg?dytm+tatc. W~&Q'.. acca&ble with near W or blue Itght. rnfdtte altOm, and conventionally far more react&e organ& mo$c~c~ lncludtng alcohofr. aIkcnea. N-alkyktcctamldts. and &tones, at campnra Onra.-dthcLnaUYactppaoZcmtpoundb~~aed"~tmdlrrtlonoi acctonlWe solutlona contamtng the polyaxotungatate and alkane substrate under anatrob%c condttlons. Compar&on of alcohol versus akane rcacUvit&a under absolute and compctittve Wncltc condftrons indtcatcs that alcohol-poIycmtu~ate prtpdpoCiptlon can be Eqwtant fn thae p-. RcacUon of cts-and trans-2-dccaloncm tn