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Anab initioinvestigation of rotation and inversion barriers in formylphosphine

✍ Scribed by James R. Damewood; Kurt Mislow

Book ID
105012231
Publisher
Springer Vienna
Year
1980
Tongue
English
Weight
446 KB
Volume
111
Category
Article
ISSN
0026-9247

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πŸ“œ SIMILAR VOLUMES

A third type of alkylamines possessing h
A third type of alkylamines possessing high nitrogen inversion–rotation barriers
✍ Anatoly M. Belostotskii; Alfred Hassner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 62 KB

A new type of alkylamines possessing high nitrogen inversion-rotation (NIR) barriers is described (in general, these are hindered cyclic amines). The increase in barrier values for these amines is caused by an increase in steric interactions in the NIR transition state due to restrictions for N-subs