An α-alkylation/reduction of ketones via radical cyclizations of β-chloroethylsilyl enol ethers
✍ Scribed by Robert D. Walkup; Robert R. Kane; Nihal U. Obeyesekere
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 297 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Although there have been several methods for one-carbon ring expansion by use of dichlorocyclopropanes, 1 the known procedures are synthetically not
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
The reduction of ct-alkyl-13-hydroxy ketones is highly syn-seleetive if carried out in THF on their Ti-alcoholate complexes with LiBI-h or L-SeleetrideCg or N-sclectride~ depending on the bulkiness of the group bound to the earbonyl group.