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An unusually facile thioallylic rearrangement - stereochemical evidence for a free radical chain mechanism

✍ Scribed by Kozikowski, Alan P.; Huie, Edward; Springer, James P.

Book ID
126126513
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
277 KB
Volume
104
Category
Article
ISSN
0002-7863

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This communication reports a novel and efficient synthesis of lepidopterene from 9-(chloromethyl)anthracene. Furthermore, the radical nature of the process is unambiguously established through the obtention of several 9-anthracenemethyl derivatives, which are formed via a common 9-anthracenemethyl r