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An unusual synthesis of a spirothioxanthene derivative

✍ Scribed by Katja Dahms; Andrei S. Batsanov; Martin R. Bryce


Book ID
104098458
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
298 KB
Volume
51
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction of diphenyl sulfone with 2,3-dibromophthalazine-1,4-dione in the presence of n-butyllithium gave a spiro-9H-thioxanthene-10,10-dioxide derivative in 45% yield, the structure of which was proved by X-ray crystallography.


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also reflected in redox potentials. The furochlorophin 1 b oxidizes to its li cation radical at 0.47 V and reduces at -1.25 V to the anion radical (determined by cyclic voltammetry. versus Ag/AgCl, in CH,CI,). In comparison with etiochlorin I,1121 1 b is easier to oxidize as well as to reduce by abo