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An unusual reaction of cis-6-hydroperoxy-5-hydroxy-5,6-dihydrothymine with ascorbic acid

โœ Scribed by Toshio Itahara


Book ID
104236100
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
125 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


When two solutions of cis-6-hydroperoxy-5-hydroxy-5,6-dihydrothymine and ascorbic acid in deuterium oxide were mixed, chemically induced dynamic nuclear polarization was observed. The reaction gave N-formyl-N'-pyruvylurea.


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The revised structure of an oxidation pr
โœ Shigenobu Matsumoto; Mitsuyoshi Matsuo; Yoichi Iitaka ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

The previously reported structure of an oxidation product obtained from the reaction of an a-tocopherol model compound(l) with KO, is revised to 6-hydroxy-2,2,6,7,8-pentamethylchroman-S(6H)-one(3) on the basis of the X-ray crystallographic and '\*O-labeling studies. An oxidation product has been ob