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An unusual dinuclear cobalt dioxygen complex with a tetradentate thioether imidazole containing ligand. Structure of [Co2(bidhx)2(O2)(OH)](NO3)3

✍ Scribed by Bouwman, Elisabeth.; Driessen, Willem L.


Book ID
121456505
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
889 KB
Volume
110
Category
Article
ISSN
0002-7863

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✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th