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An unusual dichotomy in the regioselectivity of a metal catalyzed versus thermal ene reaction

โœ Scribed by Barry M. Trost; Mark Lautens

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
195 KB
Volume
26
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

An unusual regioselectivity in the Pd-ca
An unusual regioselectivity in the Pd-catalyzed cross coupling of alkynes. A correction
โœ Barry M Trost; Janet L Gunzner; Tatsuro Yasukata ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 121 KB

Palladium catalyzed additions of terminal alkynes to alkynoates can lead from preferential to exclusive C C bond formation at the a-carbon and, in the case of ethyl 3-dimethylphenylsilylpropiolate, complete selectivity for a-attack, an unprecedented regioselectivity that requires revision of the ear