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An unusual diazonium salt reaction

โœ Scribed by J.L. Huppatz

Book ID
104245201
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
107 KB
Volume
13
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

As part of a study of the synthetic potential of the Pschorr cyclisation in heterocyclic chemistry. the pyrasole derivative (II) was examined in an attempt to prepare the hitherto unreported pyrazolo[l,2-blindole ring system. Ring-closure onto a methyl group had been

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Reactions of Alkenediazonium Salts. Part
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โœ Ivanka Szele; Michal Tencer; Heinrich Zollinger ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 714 KB

## Abstract Reactions of the title compound **1** with various nucleophiles have been studied. The salt behaves like an alkylating agent towards ethers, alcohols and water forming ethyl diazoacetate (**2**), which reacts further with excess of the nucleophile. A solvent cage mechanism accounting fo