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An Unprecedented Photochemical Cis to Trans Isomerization of Dinuclear Gold(I) Bis(diphenylphosphino)ethylene Complexes

✍ Scribed by Foley, Janet B.; Bruce, Alice E.; Bruce, Mitchell R. M.


Book ID
127013726
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
271 KB
Volume
117
Category
Article
ISSN
0002-7863

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Structure and Photochemical Isomerizatio
✍ Janet B. Foley; Stanley E. Gay; Michael J. Vela; Bruce M. Foxman; Alice E. Bruce πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 155 KB

## Abstract The crystal structures for __cis‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ and __trans‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ are reported. The structure of __cis‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ reveals a short intramolecular Au–Au distance of 2.9526(5) Γ…, while the structure of __trans__‐(Ph~2~PCH=CHPPh~2~)(