✦ LIBER ✦
An Unprecedented, Copper-Mediated, In-Situ Multi-Step Ligand Formation – Synthesis, Structure, and Magnetism of Bis(μ-methoxo)bis[nitrato(2-methoxy- methylamino-3-methylpyridine)copper(II)]
✍ Scribed by Saeid Amani Komaei; Gerard A. van Albada; Ilpo Mutikainen; Urho Turpeinen; Jan Reedijk
- Book ID
- 101278926
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 134 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
A novel chelating ligand, synthesized in situ within the 3-methylpyridine). The geometry around the copper atom is square pyramidal and the Cu-Cu distance within the coordination sphere of Cu II from 2-amino-3-methylpyridine, MeOH, and dioxygen from the air, is found to form a strongly dinuclear unit is 3.011(2) A ˚with an Cu-O-Cu angle of 103.13(8)°. Synthesis, X-ray crystal structure, and magnetism coupled, dinuclear methoxo-bridged Cu II compound with the formula [Cu(L)(CH 3 O)(NO 3 )] 2 (L = 2-methoxymethylamino-are reported.