An unexpected N-substituted oxindole: 5-methyl-1-(3,3,5-trimethyl-2-p-tolyl-1,2-oxazolidin-5-yl)-1H-indol-3(2H)-one
✍ Scribed by Parvez, Masood ;Mehrdad, Morteza ;Sureni, Hossein ;Heydari, Akbar ;Jadidi, Khosrow
- Book ID
- 104489544
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 181 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 18 H 15 ClN 2 O 2 , contains planar pyrazole, tolyl and chlorophenyl rings. Intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into dimers. The carbonyl O atom is found to be disordered.
0 -(4-methyl-1,3-thiazol-5-yl)-2-oxo-2,3,2 0 0 0 ,3 0 0 0 ,5 0 0 0 ,6 0 0 0 ,7 0 0 0 ,7a 0 0 0 -octahydro-1Hindole-3-spiro-3'-1H-pyrrolizin-2 0 0 0 -yl]prop-2-en-1-one
## Abstract magnified image Oxidation of metronidazole (**4**) with sodium dichromate yielded the corresponding 2‐(2‐methyl‐5‐nitro‐1__H__‐imidazol‐1‐yl)acetic acid (**5**) which was esterified with 1‐butanol to give butyl 2‐(2‐methyl‐5‐nitro‐1__H__‐imidazol‐1‐yl)acetate (**8**). Reaction of the l