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An unexpected molybdenum(0) complex with “MoP6” coordination: crystal structure of [Mo{P(CH2CH2PPh2)3}2] · C5H10

✍ Scribed by M. Garcìa-Basallote; P. Valerga; M.C. Puerta-Vizcaíno; A. Romero; A. Vegas; M. Martínez-Ripoll


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
414 KB
Volume
420
Category
Article
ISSN
0022-328X

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Synthesis of a New Multidentate Phosphan
✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho