An unexpected challenge: ionizable compounds in the REACH chemical space

Formation of an unusual MH− ion in the m

Formation of an unusual MH− ion in the methane negative-ion chemical ionization mass spectra of chlorprothixene and aromatic sulfur compounds

✍ Patrick S. Callery; William A. Garland; Elaine K. Fukudat 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 487 KB

The methane negative-ion chemical ionization (NCI) mass spectrum of chlorprothixene shows an unusual MHion. This ion can be accounted for by electron capture followed by H transfer from the reagent gas. The most probable site of electron attachment was concluded to be related to the sulfur atom of t