An Ultrafast Glimpse of Cluster Solvation Effects on Reaction Dynamics
β Scribed by Zhong, Q.; Castleman, A. W.
- Book ID
- 126036572
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 327 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0009-2665
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The dynamics of I2 dissociation and recombination (caging) in a macrocluster are reported, covering the femtosecond to picosecond time domain. Both the exit-channel and recombination dynamics are observed and related to solute-solvent interactions, The dissociation involves bond breakage on bound/re
The endo/exo stereoselectivity of the Diels-Alder cycloaddition between cyclopentadiene and 3-crotonoyl-2-oxazolidinone catalysed by Et 2 AlCl is temperature-and solvent-dependent. Eyring plots of ln(endo/exo) versus 1/T show different inversion temperatures (T inv ) depending on the reaction solven