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An SCF CI study of the electronic states of the sulfur dioxide dication (SO2+2)

โœ Scribed by D. Winkoun; D. Solgadi; J.P. Flament

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
386 KB
Volume
139
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The energies of electronic state of SO:+ at three different geometries have been calculated using a correlated wavefunction. These calculations are discussed in connection with recent results obtained by double-photoionization, double-charge-transfer and double-mass-spectrometry experiments. Our results predict a linear geometry for the dication in its ground state and also suggest the possibility of forming a metastable state of SO:+ by charge stripping from the singly charged ion.

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