An oxidative alkylamination of 1,3,7-triazapyrenes in the aqueous medium
✍ Scribed by Ivan Borovlev; Oleg Demidov; Nadezhda Saigakova; Sergey Pisarenko; Olesya Nemykina
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 101 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-152X
- DOI
- 10.1002/jhet.693
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✦ Synopsis
Abstract
1,3,7‐Triazapyrene and 2‐methyl‐1,3,7‐triazapyrene have shown to react with a wide range of alkylamines in the presence of an oxidant (K~3~Fe(CN)~6~) in the water solution at room temperature to give rise to the corresponding 6‐mono‐alkyl(dialkyl)amino‐ and 6,8‐bis‐dialkylamino derivatives. J. Heterocyclic Chem., (2011).
📜 SIMILAR VOLUMES
## Abstract The kinetics of the nitrosation of 1,3‐dimethyl (DMU), 1,3‐diethyl (DEU), 1,3‐dipropylurea (DPU), 1,3‐dibuthyl (DBU), and 1,3‐diallylurea (DAU) were studied in a conventional UV/vis spectrophotometer in aqueous‐perchloric acid media. The kinetic study was carried out using the initial r