The osmium-catalyzed oxidation of alcohols with molecular oxygen to give aldehydes in good to excellent yields has been developed. Best results are obtained by using a buffered two-phase system with a constant pH of 10.4. Under optimized reaction conditions a remarkable catalyst productivity (TON up
An Oxidation System for Green Chemistry: The Oxidation of Alcohols and Hydrocarbons in the Presence of Metal–Polymer Complexes
✍ Scribed by Yasuhiko Kurusu
- Book ID
- 110273859
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 324 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1053-0495
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Polymer Supported Chromium Peroxide Complexes for the Selective Oxidation of Alcohols. -The usefulness of the title reaction with a selectivity for benzylic and allylic alcohols is demonstrated. It is noteworthy that compounds such as 1-octanol, 2-phenylethanol or borneol do not react. Furthermore