An orthorhombic modification of (R)-(−)-8-hydroxy-3-methyl-3,4-dihydro-1H-2-benzopyran-1-one [(R)-(−)-mellein]
✍ Scribed by Flörke, Ulrich ;Krohn, Karsten ;Zia-Ullah, ;Hussain, Hiayat
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 190 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
An orthorhombic modification of
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The title compound, also known as intricatinol, C~17~H~14~O~5~, is a homoisoflavanoid that was isolated for the first time from the twigs and stems of __Caesalpinia digyna__ Rottler. The pyran ring is in an envelope form. O—H...O intramolecular hydrogen bonds are observed. Symmetry-related molecules
## Abstract A short stereoselective synthesis of (3__R__)‐3,4‐dihydro‐6,8‐dimethoxy‐3‐undecyl‐1__H__‐[2]benzopyran‐1‐one and derivatives isolated from __Ononis natrix__ has been described. Condensation of dodecanoyl chloride with 3,5‐dimethoxyhomophthalic acid afforded 6,8‐dimethoxy‐3‐undecylisocou