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An orthometallated cyclopentadienyl phosphine bridge in a new type of heterobimetallic complex: [(?5-C5H5)(?5-C5H4)Mo{o-C6H4P(Ph)Cr(CO)5}]X (X = Cl, I)

✍ Scribed by Rigny, Sandrine; Leblanc, Jean-Claude; Mo�se, Claude; Nuber, Bernd


Book ID
118149937
Publisher
The Royal Society of Chemistry
Year
1995
Tongue
English
Weight
272 KB
Volume
1
Category
Article
ISSN
0022-4936

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✍ Virginie Comte; Marek M. Kubicki; Claude Moïse 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB 👁 1 views

Chloro-bridged bimetallic complexes (η 5 -C 5 H 5 )[η 5 -towards Lewis bases was studied; by exposure to CO or phosphanes, a facile cleavage of the chloro bridge C 5 H 4 PPh 2 MЈ(CO) 4 ]W(µ-Cl)X [X = Cl (3), X = H (4); MЈ = Cr, W] were prepared by photochemical irradiation of (η 5 -accompanied by re