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An organometallic polyimine copolymer prepared from {η6-1,4-bis(CHO)C6H4}Cr(CO)3 and 1,3-phenylenediamine

✍ Scribed by Michael E. Wright; Charlotte K. Lowe-Ma


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
337 KB
Volume
232
Category
Article
ISSN
0020-1693

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Synthesis of η6-(4a-Methyl-1,2,3,4-tetra
✍ J. Gonzalo Rodríguez; Anahí Urrutia; Antonio Lafuente 📂 Article 📅 2001 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 51 KB

## Abstract The synthesis of η^6^‐(4a‐methyl‐1,2,3,4‐tetrahydro‐4a__H__‐carbazole)tricarbonylchromium (**3**) is described, and its reactivity with organolithium reagents have been analysed. The addition of RLi (R= H, Me, __n__‐Bu, __tert__‐Bu) to **3** affords the corresponding __endo/exo__ tricar