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An on-line determination of chlorine dioxide using chlorophenol red by gas diffusion flow-injection analysis

✍ Scribed by Hui Chen; Yanjun Fang; Li Yuan; Taicheng An


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
136 KB
Volume
11
Category
Article
ISSN
0895-7533

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✦ Synopsis


An on-line determination of chlorine dioxide (ClO 2 ) in potable water using chlorophenol red (CPR) by gas diffusion flow-injection analysis (FIA) was investigated in the presence of various chlorinated species that can occur under normal watertreatment conditions. A gas diffusion membrane is used to separate the donor (sample) stream from the acceptor (detecting) stream (the donor stream transports the sample stream to the membrane separate device, and the acceptor stream collects all of the penetrated analytes and transports quantitatively to the detector) and makes it possible for this method to eliminate interference from metal ions, as well as other oxychlorinated compounds such as chlorite and chlorate. The system is more selective for chlorine dioxide than chlorine. The linear range of ClO 2 concentration is 0-0.5 mg•mL ‫1מ‬ with a detection limit of 0.02 lg•mL ‫1מ‬ (S/N ‫ס‬ 3) and a sampling frequency of 50 h ‫1מ‬ .