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An NMR study of the structure of and the internal rotation in phenylsilane

✍ Scribed by C.L Khetrapal; Edwin D Becker


Publisher
Elsevier Science
Year
1981
Weight
393 KB
Volume
43
Category
Article
ISSN
0022-2364

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Study of the electronic structure of mol
✍ E. Clementi; H. Popkie πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 319 KB

The barrier to internal rotation for the 0" angle (using Olson and Flory's notation) in the ngar-phosphate-mgar complex, CloH IgOaP, has been obtained from ab initio computations. The barrier height at 0" = 60" is 4.5 kcalimole, a: 0" = 180" is 3.3 k&/mole and at 9" = 310" is 7.5 kcal/mole. The corr