An NMR Experiment for the Accurate Measurement of Heteronuclear Spin-Lock Relaxation Rates
โ Scribed by Korzhnev, Dmitry M.; Skrynnikov, Nikolai R.; Millet, Oscar; Torchia, Dennis A.; Kay, Lewis E.
- Book ID
- 126791605
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 289 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0002-7863
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A new magic-angle spinning NMR method for distance determination between unlike spins, where one of the two spins in question is not irradiated at all, is introduced. Relaxation-induced dipolar exchange with recoupling (RIDER) experiments can be performed with conventional double-resonance equipment
## Abstract New spinโstateโselective (S^3^) NMR pulse sequences exclusively applying crossโpolarization schemes to achieve optimum homonuclear and heteronuclear ^1^H๏ฃฟX coherence transfer are reported for the simple and accurate measurement of the magnitude and sign of heteronuclear coupling constan