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An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring-Closing Metathesis

✍ Scribed by Tim Vorfalt; Steffen Leuthäußer; Herbert Plenio

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 323 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200900935

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An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex fo

An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring-Closing Metathesis

✍ Tim Vorfalt; Steffen Leuthäußer; Herbert Plenio 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

## Abstract **NHC with EWGs for RCM**: Ruthenium complexes with two N‐heterocyclic carbenes (NHCs), one of them substituted with electron‐withdrawing groups (EWGs), are highly efficient (pre)catalysts for the synthesis of tetrasubstituted olefins and trisubstituted olefins by ring‐closing metathesi

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[(NHC)(NHCewg)RuCl2(CHPh)] Complexes with Modified NHCewg Ligands for Efficient Ring-Closing Metathesis Leading to Tetrasubstituted Olefins

✍ Volodymyr Sashuk; Lars H. Peeck; Herbert Plenio 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 380 KB

ChemInform Abstract: [(NHC)(NHCewg)RuCl2

ChemInform Abstract: [(NHC)(NHCewg)RuCl2(CHPh)] Complexes with Modified NHCewg Ligands for Efficient Ring-Closing Metathesis Leading to Tetrasubstituted Olefins.

✍ Volodymyr Sashuk; Lars H. Peeck; Herbert Plenio 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 86 KB