M , = 623.8. Triklin. Raumgruppe PT. a = 848.2(3). b = 1008.4(4), c = 128X.5(5) pm. a = 102.73(3). = 94.45(3). 7 = 106.63(3)'.
An N-Phosphino C-ThiophosphinoyI Nitrilimine as a Formal 1,4 Dipole: Synthesis of 1,2,3λ5-Diaza- and 1,2,4,3λ5-Triazaphosphinines
✍ Scribed by Michel Granier; Dr. Antoine Baceiredo; Dr. Martin Nieger; Dr. Guy Bertrand
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 618 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
From the crude product of the synthesis of the dithiadiphosphetane [RP(S)S], (with R = 2,4,6-iPr3C,H,), the trans-oxathiadiphosphetane RIS)P P(S)R has been isolated, C.,,,H,,OP,S,. X-ray structure analysis and mass spectroscopic investigations give unequivocal evidence for this structure: monoclinic
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The sodium phosphonium diylide Na[Ph~2~P(NCN)~2~] (3) − the first example of a stabilised phosphonium diylide − was synthesised by treatment of sodium diphenylphosphide with 2 equiv. of cyanic azide. Compound 3 reacted with alkyl‐ and arylammonium salts [RR′NH~2~]Cl {R = PhCH~2~, __t__B