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An MNDO study of the electrophilic aromatic substitution on trifluorobenzenes

✍ Scribed by Jan Hrušák

Publisher
Springer
Year
1990
Tongue
English
Weight
369 KB
Volume
78
Category
Article
ISSN
1432-2234

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Selective Double Functionalization of me
Selective Double Functionalization of meso-Tetraphenylporphyrin Complexes on the Same Pyrrole Unit by Tandem Electrophilic/Nucleophilic Aromatic Substitution
✍ Stanisław Ostrowski; Anna M. Raczko 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 191 KB

## Abstract The mono‐nitrated __meso__‐tetraphenylporphyrin (TPP) complex **2** could be readily functionalized on the substituted pyrrole ring with yields of up to 83%. These transformations were achieved __via__ aromatic substitution with carbanions generated from diverse functionalized compounds