A group of rhenium (I) complexes including in their structure ligands such as CF~3~SO~3~‐, CH~3~CO~2~‐, CO, 2,2′‐bipyridine, dipyridil[3,2‐a:2′3′‐c]phenazine, naphthalene‐2‐carboxylate, anthracene‐9‐carboxylate, pyrene‐1‐carboxylate and 1,10‐phenanthroline have been studied for the first time by mas
✦ LIBER ✦
An LDI-TOF and ESI mass spectrometry study of a series of β-substituted cationic metalloporphyrins
✍ Scribed by R. Kachadourian; N. Srinivasan; C. A. Haney; R. D. Stevens
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 98 KB
- Volume
- 05
- Category
- Article
- ISSN
- 1088-4246
- DOI
- 10.1002/jpp.354
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✦ Synopsis
A series of β-halogenated cationic metalloporphyrins were analyzed by LDI-TOF and ESI-MS. Although LDI-TOFMS reveals to be a good tool for the characterization of this family of metal-complexes, including the redox state of the metal, ESI-MS indicates in addition the relative tendency of such metal-complexes to be reduced.
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