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An Isolated CO2 Adduct of a Nitrogen Base: Crystal and Electronic Structures

✍ Scribed by Claude Villiers; Jean-Pierre Dognon; Rodolphe Pollet; Pierre Thuéry; Michel Ephritikhine

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
355 KB
Volume
49
Category
Article
ISSN
0044-8249

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Crystal Structure, Magnetic Properties,
Crystal Structure, Magnetic Properties, and Electronic Structure of Ni(NCNH2)4Cl2 and Co(NCNH2)4Cl2
✍ Xiaohui Liu; Peter Kroll; Richard Dronskowski 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 106 KB 👁 2 views

The crystal structures of Ni(NCNH 2 ) 4 Cl 2 and Co(NCNH 2 ) 4 Cl 2 , the first complexes with cyanamide as a neutral ligand, have been determined from single crystal data (Im3m, Z = 6, a = 1259.3(2) pm, R 1 = 0.0245 for Ni(NCNH 2 ) 4 Cl 2 and a = 1266.3(2) pm, R 1 = 0.0241 for Co(NCNH 2 ) 4 Cl 2 ;