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An iodine reaction and a mercury reaction of photographic importance

โœ Scribed by Steigmann, A.

Publisher
Wiley (John Wiley & Sons)
Year
1942
Weight
394 KB
Volume
61
Category
Article
ISSN
0368-4075

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Discrimination of Enantiotopic Iodine At
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An enantioselective iodine/magnesium exchange reaction between the diiodoalkane 4 and a chiral Grignard reagent 12 has been realized at ร€ 78 8C in THF. The resulting a-iodoalkylmagnesium reagents 13 are configurationally stable under these conditions and during trapping by a benzaldehyde/dimethylalu