An investigation of spin-Hamiltonian parameters for Pd2+ ions in trigonal sites of CsMgCl3 crystals
β Scribed by Feng Wen-Lin; Wu Xiao-Xuan; Zheng Wen-Chen
- Book ID
- 117982719
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 156 KB
- Volume
- 479
- Category
- Article
- ISSN
- 0925-8388
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π SIMILAR VOLUMES
The complete high-order perturbation formulas based on a two-mechanism [i.e., crystal-field (CF) and charge-transfer (CT) mechanisms, the latter is neglected in the widely-used CF theory] model for the spin-Hamiltonian (SH) parameters (g factors g // , g ? and the hyperfine structure constants A //
The spin-Hamiltonian parameters, g factors g J and g ? and hyperfine structure constants 161 A J , 161 A ? , 163 A J and 163 A ? , for Dy 3 + ion at the tetragonal (S 4 ) Ca 2 + site of CaWO 4 crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman (or magn