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An investigation into the role of chloro-substituents in hydrogen-bonded crystals: The crystal structures of the dichlorophenols

✍ Scribed by Noel W. Thomas; Cautam R. Desiraju


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
308 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis


A graphical analysis 1~~1s been made of hydrogen-bonding patterns 2nd non-bonded interxrions in the crystnl srrucrures of the six dichlorophenols. This shows that hydrogen bonding is the primary interaction in srsbilisinz all the isomers, and that C...C and CI...CI non-bonded interactions arc also important in stabiiising structures characterised by a short (==4 3) * The term "fl-structure" has arisen since the P-polymorph of trans-cinnamic acid is characterised by a 4 -4 short axis.


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