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An Inverse Carbon Isotope Effect on The Ionization of Triphenylmethyl Chloride. Kinetic Isotope Effects on SN1 and SN2 Reactions

✍ Scribed by Kresge, A. J.; Lichtin, N. N.; Rao, K. N.


Book ID
126929314
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
300 KB
Volume
85
Category
Article
ISSN
0002-7863

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## Abstract Multistep hydrogen isotope exchange reactions, such as the Γ­onization of a carbon acid via a carbanion intermediate in a protic solvent, when conducted using an isotopic tracer to monitor the exchange, have the unusual feature that their rate‐determining steps always refer to the transf