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An intramolecular Diels-Alder approach to the cis ring fused isomer of the 25-hydroxy vitamin D2 Grundmann ketone

โœ Scribed by Wilson, Stephen R.; Jacob, Linda


Book ID
127174114
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
823 KB
Volume
57
Category
Article
ISSN
0022-3263

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Intramolecular diels-alder reactions of
โœ Daniel L. Comins; Abdul H. Abdullah; Roy K. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 181 KB

In refluxing decalin P-alkenyl-1-alkoxycarbonyl-1,2\_dihydropyridines undergo an intramolecular Diels-Alder reaction to provide novel polycyclic compounds. The cis-decahydroquinoline ring system can be prepared from the appropriate Diels-Alder product utilizing a ring-opening reverse Mannich reactio