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An Intramolecular Allenic [2 + 2 + 1] Cycloaddition

โœ Scribed by Brummond, Kay M.; Wan, Honghe; Kent, Joseph L.


Book ID
127315543
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
260 KB
Volume
63
Category
Article
ISSN
0022-3263

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8icyclo[3.2.l]octa-3,6-dien-2-ones photoisomerize to ketenes (J + 2; ,4 + 0): When the ketene is hfghly substituted, as in the octamethyl derivative ,$' or is unusually reactive, as in the chloroketene :), intramolecular cycloaddition (GZs + n2a) competes successfully with attack by external nucleop