An interpretation of the mean spherical approximation
✍ Scribed by E. Martina; F. del Río
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 163 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0375-9601
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📜 SIMILAR VOLUMES
We present a method for calculating electrostatic energies of an ionic micellar solution under the conditions of quasi-spherical micelles and point-like counterions. It is based on a multicomponent mean spherical approximation (MMSA) theory with non-additive diameters. The partial structure factors
The Helmholtz free energy of ionic solutions is calculated in the dressed-ion theory (DIT) using a Gibbs-Helmholtz relation. The obtained expression naturally takes into account the occurrence of a process of renormalization of charges and screening length in the bulk which is described by means of