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An insight into the C–S coupling mechanism of aryl Grignard reagents with aryl arenesulfonates

✍ Scribed by Fatma Eroğlu


Book ID
106513244
Publisher
Springer-Verlag
Year
2011
Tongue
English
Weight
253 KB
Volume
103
Category
Article
ISSN
1878-5190

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Nickel catalyzed cross-coupling of modif
✍ Joseph A Miller; John W Dankwardt 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 120 KB

The nickel catalyzed cross-coupling of alkyl and alkenyl Grignard reagents with aryl nitrile derivatives affords good yields of the corresponding aryl alkanes or aryl alkenes via activation of the C CN bond. To prevent direct addition of the nucleophile to the nitrile group, the reactivity of the Gr