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An Infrared and 31P Magic Angle Spinning Nuclear Magnetic Resonance Study of the Adsorption of PCl3 and OPCl3 on Silica

โœ Scribed by Morrow, B. A.; Lang, S. J.; Gay, Ian D.


Book ID
127170352
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
529 KB
Volume
10
Category
Article
ISSN
0743-7463

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Magic-angle spinning nuclear magnetic re
โœ M.W.G. Lockyer; D. Holland; A.P. Howes; R. Dupree ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 900 KB

Some PbO-Al2O3-P2O5 glasses have been investigated using 31P and 27Al magic-angle spinning nuclear magnetic resonance. The observed spectra could be divided into two groups. In the first, Al(IV), Al(V) and Al(VI) are observed, the 31P linewidths are large and the chemical shift range (-30 to -36 ppm