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An inexpensive modification of the Simmons-Smith reaction: The formation of bromomethylzinc bromide as studied by NMR spectroscopy

✍ Scribed by Bodo Fabisch; Terence N. Mitchell


Book ID
103221817
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
147 KB
Volume
269
Category
Article
ISSN
0022-328X

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The fragmentation and redistribution reactions of [Rh 4 (CO) 12-x {P(OPh) 3 } x ] (x = 1-4) with carbon monoxide have been studied using high-resolution, high-pressure NMR spectroscopy. Under the conditions of efficient gas mixing in a high-pressure NMR bubble column, [Rh 4 (CO) 9 {P(OPh) 3 } 3 ] fr