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An in situ radiolysis time-resolved electron spin resonance study of 2-methyl-2-nitrosopropane spin trapping kinetics

โœ Scribed by Madden, Keith P.; Taniguchi, Hitoshi


Book ID
126231746
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
942 KB
Volume
113
Category
Article
ISSN
0002-7863

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โœ Mikio Yagi; Yasuaki Deguchi; Yasushi Shioya; Jiro Higuchi ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 368 KB

Time-resolved ESR spectra have been observed for the lowest triplet states of 2,2'-bipyridine (bpy) and singly protonated bpy (bpyH+) in ethanol at 77 K. With the aid of computer simulation, it is concluded that the T, sublevel is most active in S, +T, intersystem crossing in both molecules studied