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An improved variant of the julia olefin synthesis: reductive elimination of β-hydroxy imidazolyl sulfones by samarium dhodide

✍ Scribed by Andrew S. Kende; José S. Mendoza


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
235 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reductive elimination reaction of p-hydroxy imidazolyl sulfones 1 to afford the corresponding olefins can be accomplished under mild conditions and in good yields using SmI2, offering a convenient modification of the Julia olefm synthesis.