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An Improved Synthesis of N-Isocyanoiminotriphenylphosphorane and Its Use in the Preparation of Diazoketones.

✍ Scribed by Matthew M. Bio; Gary Javadi; Zhiguo Jake Song


Publisher
John Wiley and Sons
Year
2005
Weight
18 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract D‐Glyceraldehyde 3‐phosphate (=D‐GAP; **2**) was prepared by an improved chemical method (__Schemeβ€…2__), and it was then employed to synthesize 1‐deoxy‐D‐xylulose 5‐phosphate (=DXP; **3**) which is enzymatically one of the key intermediates in the MEP (**4**) terpenoid biosynthetic path